and it looks interesting.
New phases in supercritical fluids: the Widom line as crossover between liquid-like and gas-like behaviour
According to textbooks, there is no observable physical characteristic beyond the critical point allowing a liquid to be distinguished from a gas, hence only a single fluid phase is defined. Using inelastic X-ray scattering and molecular dynamics simulations, a team lead by Italian researchers from the Universities of Rome and Florence, identified two distinct dynamical regimes (liquid-like and gas-like) in dense hot supercritical fluid argon, contradicting the notion of a homogeneous supercritical fluid phase.
The properties of fluids in the supercritical regime are mostly unknown despite intense research efforts throughout the past century. This region is above the critical point, the thermodynamic point in pressure (Pc) and temperature (Tc) above which distinction between liquid and gas phases was thought not to exist. Research on fluids was typically hampered by technical difficulties encountered with complex sample environments such as high pressure diamond anvil cells or laser shock techniques.
Where is the distinction between liquid and gas in a supercritical fluid?
Important new insights were recently gained through an experiment on supercritical argon (at T=4×Tc and P>102×Pc), conducted on beamline ID28, in conjunction with molecular dynamics simulations, which revealed distinct changes in the dispersion of nanometric acoustic waves depending on the thermodynamic conditions. This dynamical feature represents the so-called positive sound dispersion, observed for most liquids when measuring the sound velocity as a function of wavelength from the continuum limit (at very large wavelengths) in which acoustic waves propagate adiabatically, to the short-wavelength limit, that is, when approaching interparticle distances. Its origin can be traced back to the presence of at least one relaxation mechanism interacting with the dynamics of the density fluctuations induced by the propagation of acoustic waves. In particular the viscoelastic relaxation, reflecting the interaction of local structural changes (on nm length- and picosecond time scales) with acoustic sound waves, provides a clear fingerprint of liquid behaviour .
Figure 1 reports the amount of positive sound dispersion, corresponding to the maximum of the ratio of the largest observed sound velocity over its adiabatic value, as a function of pressure, derived from the experiment and molecular dynamics simulations. A sharp decrease from about 13% to 4% is observed on pressure decrease with a cross-over located at 0.4 GPa. This distinct decrease is due to the disappearance of the structural relaxation process, and thus marks the transition from a collective liquid-like to a single particle gas-like behaviour. This clearly provides a connection between dynamics and thermodynamics, contradicting the widespread belief of a homogeneous supercritical fluid phase. Furthermore, we speculate that the positive sound dispersion plays the role of an order parameter, sensitive to the local structure and able to amplify on a macroscopic scale the degree of correlation between thermal heterogeneities and mechanical density fluctuations.
Figure 1. Positive sound dispersion of argon as a function of pressure at 573 K. Full and open circles indicate the positive sound dispersion as obtained from the IXS experimental data and from the molecular dynamics simulations, respectively. The two solid lines represent fits to the data set below and above the cross-over point at 0.4 GPa, and the dotted line marks the point on the extrapolated Widom line at 573 K.
Figure 2. Sketch of the (P/Pc, T/Tc) plane. Red line: Widom line of argon obtained from the NIST database  (continuous) up to the highest temperature where a maximum in CP vs. P can still be identified (T=470 K; T/Tc=3.12), and extrapolated (dotted) above this temperature. Black line: best fit of the average of the liquid-vapour coexistence lines for argon, neon, nitrogen and oxygen using the Plank-Riedel equation . Dots with different colours mark data from a variety of systems (this study, and also ref.  and references therein). Isothermal, experimental and molecular dynamics simulation data on argon are reported in pink inside a black rectangle. Open circles represent cases where the positive dispersion of the sound velocity exhibits low values, full circles cases where there is a clear signature of large positive dispersion.
 T. Scopigno, G. Ruocco, and F. Sette, Rev. Mod. Phys. 77, 881 (2005).
 F. Gorelli, M. Santoro, T. Scopigno, M. Krisch, and G. Ruocco, Phys. Rev. Lett. 97, 245702 (2006).
 NIST Chemistry WebBook,
 R. Plank and L. Riedel, Ingenieur-Archiv 16, 255 (1948).
Principal publication and authors
G.G. Simeoni (a), T. Bryk (b,c), F.A. Gorelli (d,e), M. Krisch (f), G. Ruocco (e,g), M. Santoro (d,e) and T. Scopigno (e,g), The Widom line as the crossover between liquid-like and gas-like behaviour in supercritical fluids, Nature Physics 6, 503 (2010).
(a) FRM II, Technische Universität München, Garching (Germany)
(b) Institute for Condensed Matter Physics, National Academy of Sciences of Ukraine, Lviv (Ukraine)
(c) National Polytechnic University of Lviv (Ukraine)
(d) LENS, European Laboratory for Non Linear Spectroscopy, Firenze (Italy)
(e) IPCF-CNR, UOS Roma (Italy)
(g) Università di Roma ‘La Sapienza’ (Italy)